Carolynne R. Hagan - Storming Media

Synthesis, Characterization and Immobilization of Nanocrystalline Binary and Ternary III-V (13-15) Compound Semiconductors

20 DEC 95

24 pages

Authors: Lara I. Halaoui; Shreyas S. Kher; Michael S. Lube; Steven R. Aubuchon; Carolynne R. Hagan; DUKE UNIV DURHAM NC DEPT OF CHEMISTRY

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Two synthetic routes to nanocrystalline III-V (13-15) materials are discussed. The first employs dehalosilylation reactions between Group III trihalides and E(SiMe3)3 (E = P, As) in hydrocarbon solvents affording nanocrystalline III-V semiconductors or their precursors. The second involves reactions of MX3 (M = Ga, X = Cl, I; M = In, X = Cl, I) in glymes with in situ synthesized (Na/K)3E (E = P, As, Sb) in aromatic solvents, ...