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Detection and CountermeasuresActive & Passive Radar Detection & Equipment

The Properties of Evaporated Gold and Tungsten Oxides

Authors: P. G. Wilkinson; NAVAL RESEARCH LAB WASHINGTON DC
 
Abstract: Gold blacks prepared by evaporating gold from a tungsten filament in tank nitrogen at several millimeters pressure were found to contain tungsten oxides which greatly affected the optical and electrical properties. Deposits containing more than 0. 5 mol% of tungsten oxides were black and showed resistivities 10(exp 3) to 10(exp 8) times that of bulk gold. The resistivities of gold black increased on exposure to oxygen. On the other hand, oxide-free deposits were yellow and possessed a 10% stable resistivity, unaffected by exposure to oxygen. Exposure to air or oxygen caused an increase in the electrical resistance and optical transmission of films of tungsten dioxide and tungsten trioxide evaporated in high vacuum. It was concluded that evaporated films of pure gold are unaffected by exposure to air, and that the changes in optical and electrical characteristics often observed in evaporated gold films exposed to air may be attributed to contamination by oxides of tungsten. jg p.4

Limitations: APPROVED FOR PUBLIC RELEASE
Description: Interim rept.
Pages: 16
Report Date: 01 AUG 50
Report Number: A773592
Keywords relating to this report:
*EVAPORATION
*GOLD
*TUNGSTEN OXIDES
ABSORBERS_MATERIALS_
AIR
BLACK_COLOR_
BOLOMETERS
COATINGS
CONTAMINATION
DIOXIDES
ELECTRICAL PROPERTIES
ELECTRICAL RESISTANCE
EXPOSURE_GENERAL_
FILAMENTS
HIGH VACUUM
LIGHT TRANSMISSION
NITROGEN
OPTICAL PROPERTIES
OXIDES
OXYGEN
PURITY
RADIATION
THERMOCOUPLES
TUNGSTEN
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