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Physics and AstronomyMechanics

The Low-Temperature Vibrational Behavior of Pentaerythritol Tetranitrate

Authors: Jennifer A Ciezak; Timothy A Jenkins; ARMY RESEARCH LAB ABERDEEN PROVING GROUND MD WEAPONS AND MATERIALS RESEARCH DIRECTORATE
Abstract:
The authors report the room temperature Raman and synchrotron Fourier transform infrared measurements of pentaerythritol tetranitrate (PETN), as well as low-temperature Raman measurements from 4 to 298 K up to 15 GPa, using a helium gas pressure medium. No evidence of phase transitions was observed in the pressure/temperature range studied, although the molecular symmetry of PETN is modified from S4 to D2 near 8.1 GPa. The modification was not found to be temperature dependent, and decompression studies indicated the reversibility of the symmetry change.

Limitations: APPROVED FOR PUBLIC RELEASE
Description: Final rept. Jan 2007-Oct 2007
Pages: 24
Report Date: Jun 2008
Report Number: A703584
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