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ChemistryOrganic Chemistry

Formation of Hydrocarbons from Carbon Monoxide on Rhodium/Alumina Model Catalysts.

Authors: R. M. Kroeker; W. C. Kaska; P. K. Hansma; CALIFORNIA UNIV SANTA BARBARA QUANTUM INST
Abstract:
Adsorbed hydrocarbons are produced when tunnel junctions containing carbon monoxide chemisorbed on rhodium/alumina are heated. Two different species can be produced with different reaction conditions. Isotopic substitution with C13O16 and 12C18O, and reference to published spectra allow their identification as formate ions and an ethylidene species. (Author)

Description: Technical rept.
Pages: 19
Report Date: 22 DEC 1978
Contract Number: N0001478C0011
Report Number: A584460

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Keywords relating to this report:
ADSORPTION
ALKYNES
ALUMINUM OXIDES
CARBON MONOXIDE
CATALYSTS
CHEMISORPTION
FORMATESZ
FORMATESZALUMINUM OXIDES
HYDROCARBONS
ISOTOPES
RHODIUM
SYNTHESIS(CHEMISTRY)
TRANSITION METALS
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