|
Abstract:
The vibrational frequencies of halogens adsorbed on Ag(100) are calculated. The frequency of a single adsorbed atom vibration perpendicular to the surface is obtained from AgX (X = F, Cl, Br, I) crystal frequencies. Interaction between dipoles consisting of the effective charge on the adsorbed atom and its induced image charge produces a coverage dependent frequency. The effective charge on the adsorbed atom is assumed to be 1.0 e, while the electronic polarizability of the real-plus-image atom system is assumed to be twice the electronic polarizability of X-. At full coverage, the calculated frequencies for the k = O modes are 437, 241, 150, and 113/cm respectively for X = F, C, Br, I, which compare well with experimental values, and these frequencies are assigned to external vibrational modes of halogen atoms adsorbed on silver. (Author)
| Description: |
Technical rept. |
| Pages: |
23 |
| Report Date: |
17 JUL 1980 |
| Contract Number: |
N0001477C0209, DAAG2977G0020 |
| Report Number: |
A466780 |
Report Unavailable |
| This title is unavailable from Storming Media. We do not know when it might be available, if at all. We list the report on our site for bibliographic completeness, to help our users know what other work has been performed in this field. Please note that as with all titles on this site, we do not have contact information for any of the authors. Nor can we give any suggestions on how one might obtain this report. |
|
|
|
|
|
Keywords relating to this report:
Email This Abstract
