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An Investigation of the Initiation Stage of Hot Corrosion in Ni-Base Alloys

Authors: T. T. Huang; G. H. Meier; PITTSBURGH UNIV PA DEPT OF METALLURGICAL AND MATERIALS ENGINEERING
Abstract:
The results of this study have shown that the initiation of hot corrosion attack of IN-738 and similar alloys is the result of local penetration of the molten salt through the protective oxide scale. This penetration occurs at sites where alloy carbides have been incorporated in the scale. The mechanism of scale breakdown may be that the carbide provides a physical discontinuity in the scale or that it provides a site where the salt may become very acid and dissolve the Cr(Sub 2)O(Sub3) scale. The observation that the effectiveness of the carbides in initiating scale breakdown is influenced strongly by their composition suggests the latter mechanism may be the most important.

Description: Semi-Annual Rept. No. 2, 1 Mar-31 Aug 79
Pages: 45
Report Date: NOV 79
Contract Number: NSG-3214
Report Number: D397811

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