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Physics and AstronomyAtomic and Molecular Physics and Spectroscopy

Spectroscopy of Selected Diatomic Metal and Metal-Oxide Molecules Using Laser Excited Fluroescence.

Authors: Stanley Ernest Johnson; CALIFORNIA UNIV SANTA BARBARA DEPT OF PHYSICS
Abstract:
A laboratory system has been developed for the gas phase production of diatomic metal-oxides, and a program has been initiated for the spectroscopic study of these molecules using the techniques of laser excited fluorescence. Metal-oxides were produced from the following metals: Al, Ba, Be, Mg, Fe, Pb, and Sn. These molecules were produced chemically in a flowing gas system by mixing metal vapor with an oxidant. Chemiluminescence invariably accompanied the formation of metal-oxides in this system. Laser excited fluorescence was shown to be useful for determining molecular constants, studying collisional processes, and for measuring radiative lifetimes and quenching cross sections. (Author)

Description: Doctoral thesis
Pages: 196
Report Date: DEC 1971
Contract Number: AFAFOSR185170
Report Number: 0357737

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Keywords relating to this report:
*FLUORESCENCE
*ULTRAVIOLET SPECTRA
ALUMINUM COMPOUNDS
BARIUM COMPOUNDS
BERYLLIUM COMPOUNDS
CHEMILUMINESCENCE
DIATOMIC MOLECULES
ELECTRON TRANSITIONS
EXCITATION
LASERS
LEAD COMPOUNDS
MAGNESIUM OXIDES
MOLECULAR ENERGY LEVELS
OXIDES
RELAXATION TIME
SYNTHESIS_CHEMISTRY_
THESES
TIN COMPOUNDS
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