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Physics and AstronomyAtomic and Molecular Physics and Spectroscopy

THERMAL DISSOCIATION OF HF IN A SHOCK TUBE. PART I. DISSOCIATION BEHIND REFLECTED SHOCK WAVES USING IR ABSORPTION,

Authors: J. F. Spinnler; ROHM AND HAAS CO HUNTSVILLE AL REDSTONE RESEARCH LABS
Abstract:
The rate of dissociation of HF in Argon was measured using infrared absorption of the transition of the 2.5 microns absorption band of HF in a shock tube behind reflected shock waves. High-speed chopping (60 kcps) was used to differentiate between absorbed and emitted radiation. Computer programs allowed correction for HF line (pressure) broadening as a function of temperature and total pressure and for HF association.

Pages: 87
Report Date: 13 APR 1967
Contract Number: DAAH0167C0655
Report Number: 0340218

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Keywords relating to this report:
(DISSOCIATION
(REACTION KINETICS
ABSORPTION
ABSORPTION SPECTRA
APPROXIMATION(MATHEMATICS)
CALIBRATION
COMPUTER PROGRAMS
DISSOCIATION)
EMISSIVITY
FLUORIDES
GAS ANALYSIS
GAS CHROMATOGRAPHY
GAS FLOW
HYDROGEN COMPOUNDS)
INFRARED RADIATION
LEAST SQUARES METHODZ
LEAST SQUARES METHODZREACTION KINETICS
MONOCHROMATORS
RECOMBINATION REACTIONS
SHIFTING EQUILIBRIUM FLOW
SHOCK TUBES
SHOCK WAVES
TEST EQUIPMENT
TEST METHODS
THERMAL SHOCK
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