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Materials SciencesProperties of Metals and Alloys

TERNARY PHASE EQUILIBRIA IN TRANSITION METAL-BORON-CARBON-SILICON SYSTEMS. PART II. TERNARY SYSTEMS. VOLUME IX. ZR-W-B SYSTEM AND THE PSEUDOBINARY SYSTEM TAB2-HFB2.

Authors: Y. A. Chang; AEROJET-GENERAL CORP SACRAMENTO CA MATERIALS RESEARCH LAB
Abstract:
The solid state phase equilibria of the system Zr-W-B at 1400 C and the phase equilibria in the melting range for the four pseudobinary systems: ZrB2-W2B5-ZrB2-WB, ZrB2-W2B and ZrB2-W have been investigated using X-ray technique, melting point determinations and metallographic examinations. At 1400 C, the intermetallic phase ZrW2 and the four tungsten-boron intermediate phases were found to be in equilibrium with ZrB2. Two ternary phases, one possibly stable only at high temperatures, were indicated to exist in this system. The pseudobinary system, TaB2-HfB2 forms a series of continuous solid solutions. The melting points increase smoothly from pure TaB2 to HfB2. (Author)

Description: Technical rept.
Pages: 26
Report Date: FEB 1966
Contract Number: 615, AF336151249
Report Number: 0041984

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Keywords relating to this report:
(BORIDES
(TANTALUM COMPOUNDS
(TRANSITION METALS
BORIDES)
BORON ALLOYS
CRYSTAL LATTICES
EUTECTICS
HAFNIUM COMPOUNDS)
INTERMETALLIC COMPOUNDS
MELTING POINTZ
MELTING POINTZPHASE STUDIES)
PHASE STUDIES)
PHOTOMICROGRAPHY
SOLID SOLUTIONS
TUNGSTEN ALLOYS
TUNGSTEN COMPOUNDS
X RAY DIFFRACTION
ZIRCONIUM ALLOYS
ZIRCONIUM COMPOUNDS
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