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Materials SciencesProperties of Metals and Alloys

Prevention of Corrosion in Structural Aluminum Alloys

Authors: K. Sieradzki; R. W. Carpenter; R. C. Newman; N. Dimitrov; T. J. Leclere; ARIZONA STATE UNIV TEMPE DEPT OF MECHANICAL AND AEROSPACE ENGINEERING
Abstract:
We examined the general phenomenology associated with the corrosion of Al Alloy 2024-T3. Copper redistribution is controlled by S-phase dealloying and matrix dealloying. Matrix dealloying of aluminum occurs owing to the increased pH that develops at the alloy/electrolyte interface owing to oxygen reduction. We summarize results of a detailed investigation aimed at determining the mechanism and magnitude of the oxygen diffusion limited current density during corrosion of Al Atloy 2024-T3. Our results show that oxygen reduction occurs via the standard 4-electron mechanism and that the oxygen diffusion - limited current density has a value of approx. 25 uA cm(-2).

Limitations: APPROVED FOR PUBLIC RELEASE
Description: Final technical rept. Sep 1996-31 Oct 2002
Pages: 59
Report Date: 31 OCT 2002
Contract Number: F496209610475
Report Number: A035804
Keywords relating to this report:
*CORROSION INHIBITION
ALUMINUM ALLOYS
COPPER
DIFFUSION
ELECTROCHEMISTRY
ELECTROLYTES
OXYGEN
REDUCTION
STRUCTURAL PROPERTIES
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