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Materials SciencesLaminates and Composite Materials

Transparent Nanoporous Glass-Polymer Composite for U.S. Army Applications

Authors: Daniel J O'Brien; Thomas F Juliano; Parimal J Patel; Steven H McKnight; ARMY RESEARCH LAB ABERDEEN PROVING GROUND MD
Abstract:
This report explores the manufacturing of a novel transparent polymer-glass composite. The material is created by infiltrating nanoporous glass (Vycor, Corning Inc.) with different polymers. The Vycor pores (4-6 nm) are much smaller than the wavelength of light thus, refractive index matching with the polymer is not necessary for transparency. Close to 90% of the pore volume can be filled by soaking the porous glass in methyl methacrylate and polymerizing in situ. The resulting composite is 95% transparent with excellent clarity, extremely low haze, and an elastic modulus that is well predicted by micromechanics.

Limitations: APPROVED FOR PUBLIC RELEASE
Description: Final rept. Oct 2005-Sep 2006
Pages: 22
Report Date: Oct-2008
Report Number: A000494
Keywords relating to this report:
*GLASS
*POLYMERS
ARMOR
HAZE
METHACRYLATES
MICROMECHANICS
MILITARY APPLICATIONS
MODULUS OF ELASTICITY
POLYMERIZATION
POROUS MATERIALS
REFRACTIVE INDEX
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